• International Journal of Technology (IJTech)
  • Vol 14, No 3 (2023)

Comparison of Phase Change Materials of Modified Soy Wax using Graphene and MAXene for Thermal Energy Storage Materials in Buildings

Comparison of Phase Change Materials of Modified Soy Wax using Graphene and MAXene for Thermal Energy Storage Materials in Buildings

Title: Comparison of Phase Change Materials of Modified Soy Wax using Graphene and MAXene for Thermal Energy Storage Materials in Buildings
Titin Trisnadewi, Eny Kusrini, Dwi Marta Nurjaya, Byrne Paul, Maré Thierry, Nandy Putra

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Cite this article as:
Trisnadewi, T., Kusrini, E., Nurjaya, D.M., Paul, B., Thierry, M., Putra, N., 2023. Comparison of Phase Change Materials of Modified Soy Wax using Graphene and MAXene for Thermal Energy Storage Materials in Buildings. International Journal of Technology. Volume 14(3), pp. 596-605

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Titin Trisnadewi Applied Heat Transfer Research Group, Department of Mechanical Engineering, Universitas Indonesia, Depok, West Java 16424, Indonesia
Eny Kusrini Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Depok, West Java 16424, Indonesia
Dwi Marta Nurjaya Department of Metallurgical and Material, Faculty of Engineering, Universitas Indonesia, 16424 Depok, West Java, Indonesia
Byrne Paul Civil and Mechanical Engineering Laboratory LGCGM, University of Rennes, Rennes, France, 35704
Maré Thierry Civil and Mechanical Engineering Laboratory LGCGM, University of Rennes, Rennes, France, 35704
Nandy Putra Applied Heat Transfer Research Group, Department of Mechanical Engineering, Universitas Indonesia, Depok, West Java 16424, Indonesia
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Abstract
Comparison of Phase Change Materials of Modified Soy Wax using Graphene and MAXene for Thermal Energy Storage Materials in Buildings

This study aimed to characterize Phase Change Materials (PCM) by improving their properties using shape stabilization; this was achieved by adding nanoparticles as a support material. PCM soy wax was modified using two nanoparticles, graphene, and MAXene Ti3AlC2. The synthesis process comprised stirring using a magnetic stirrer and ultrasonication using an ultrasonic processor with various percentages of 0.1, 0.5, and 1 wt.% of soy wax with nanoparticles. Based on the results, the morphologies of graphene and MAXene Ti3AlC2 were found to be in the form of sheets. These sheets had a large surface area, so soy wax could adsorb more nanoparticles to increase the stability of the material. The thermal conductivity increased with increasing percentage addition of nanoparticles. The highest values from the synthesis with graphene and MAXene Ti3AlC2 were 0.89 W/mK and 0.85 W/mK, respectively. The thermal conductivity of soy wax increased with the ratio of pure soy wax and nano-soy wax; the thermal conductivity was 6.01 for soy wax+graphene and 5.71 for soy wax+Ti3AlC2. Differential scanning calorimetry (DSC) results showed an increase in the melting and solidifying points of pure soy wax. The modified soy wax with 0.1 wt.% graphenes experienced a reduction in the melting and solidification points up to 15% and 14%, respectively. Similar results were obtained for 0.1 wt.% MAXene Ti3AlC2. In this case, there was a reduction in the melting and solidifying points by 16% and 13%, respectively. Finally, the addition of MAXene improved the material stability and thermal conductivity of soy wax and has the potential to be used as a thermal energy storage material for building applications.

Graphene; MAXene; Phase change material; Soy wax; Thermal energy storage

Introduction

    The ever-increasing world population, combined with the considerable increase in energy demand, has resulted in an environmental crisis (Vennapusa et al., 2020). One sector that consumes a significant amount of energy is buildings, where the maximum energy is utilized for the heating and cooling systems (Imessad et al., 2014). The demand for the installation of cooling systems in buildings is growing rapidly in the tropics. This is because the climate zones that receive large amounts of solar radiation have longer sunny days, high humidity, and high temperatures (Al-Obaidi et al., 2014). According to the Regulation of the Ministry of Health of the Republic of Indonesia 2011, it states that the standard temperature range for comfort buildings in Indonesia is 18-30oC. Heat absorption in buildings that are quite high in the tropics causes uncomfortable conditions for humans who are indoors. The uncomfortable thermal conditions can also be caused by the building itself due to the materials used for construction. Currently, many studies have been reported on building materials that can be used in passive methods for achieving energy efficiency and thermal comfort (Latha et al., 2015).

        Thermal Energy Storage (TES) has been widely used to address fluctuations in energy demand and supply gaps. There are three forms of TES: Latent Heat Thermal Energy Storage (LHTES), Sensible Heat Thermal Energy Storage (SHTES), and thermochemical storage systems (Nomura et al., 2015). Phase Change Materials (PCM) are TES materials currently in great demand by researchers owing to their large thermal energy storage capacity during the charging and discharging processes (Jamekhorshid et al., 2014). The correct use of PCM in the building can minimize peak cooling loads, allow the use of smaller HVAC technical equipment for cooling, and maintain the indoor temperature within a comfortable range owing to smaller indoor temperature fluctuations (Souayfane et al., 2016). Many studies have been related to the application of PCM, especially in buildings. (Zhang et al., 2017) used PCM composites as a substitute for sand, (Laaouatni et al., 2016) used PCM to build optimal walls made of concrete blocks filled with PCM and ventilated tubes, and (Saikia et al., 2018) incorporated PCM into concrete walls to reduce the increase in heat and temperature fluctuations in the buildings.

        PCM are grouped into three types: organic, inorganic, and eutectic (Kant et al., 2016). Fatty acids as organic PCM have several advantages. It has a large storage capacity, abundant in nature, non-toxic, not harmful to health, non-corrosive, and exhibits low supercooling (Rasta and Suamir, 2018). However, organic PCM has low conductivity and the possibility of leakage during the phase-change process (Huang et al., 2017). The stabilized form of PCM is used to eliminate losses and increase the PCM efficiency in terms of thermal and physical properties.  The incorporation of nanomaterials into pure PCM can significantly increase their thermal conductivity and stability (Kalaiselvam and Parameshwaran, 2014). Many researchers have carried out mixing PCM with nanomaterials. In a study by (Amin et al., 2017),  beeswax PCM was mixed with graphene nanoparticles; (Meng et al., 2013) synthesized a fatty acid/CNT composite, (Wi et al., 2015) studied shape-stabilized phase change materials using fatty acid esters and exfoliated graphite nanoplatelets, and (Kim et al., 2016) synthesized octadecane/expanded graphite composites. Thus, several studies have been conducted to enhance nano-PCM's material stability and thermal conductivity.

        Graphene is the world’s thinnest material—a single layer of carbon atoms that has excellent electrical properties graphene can make it play a large role in energy storage, material composites, sensors, and other fields. The structure of graphene, consisting of layers, makes graphene highly conductive with carrying mobility of up to 200,000 cm2V-1 s -1 and thermal conductivity of up to 5,300 Wm-1K -1  (Kusrini et al., 2019). The new two-dimensional material, MAXene, has hydrophilic properties, excellent oxidation resistance, high thermal and electrical conductivity, high thermal stability, and high surface area (Naguib et al., 2012). Appropriate shape stabilization methods are required to achieve the desired modifications in the thermal stability of materials using nanoparticles. The shape-stabilized PCM (SSPCM) method is divided into three: mixing, ultra-sonification, and impregnation (Lee et al., 2018). Mixing is one of the simplest, but there is no stable connection or bond between the PCM and the supporting material. Ultra-sonification is a method performed by injecting a PCM into the pores of the supporting material (Kusrini et al, 2019). Impregnation is a method that removes gas and moisture from pores and then injects them with the PCM (Putra et al., 2019). The discovery and identification of PCM properties are very important because PCM has several benefits and applications that can solve energy problems. In this study, the organic properties of a PCM were modified to improve its thermal properties. The organic PCM selected in this study was derived from a group of waxes, namely soy wax, because it has a temperature range close to room temperature, so it has the potential to be applied on a wide scale. Based on its application as a heat energy storage material in buildings subjected to repeated heating and cooling cycles, it is very important to know the durability of a PCM. In a study conducted by (Trisnadewi et al., 2021), pure soy wax thermal cycle test results were obtained. Thermal cycling tests were performed with heating and cooling cycles of 0, 500, 1000, 3000, and 5000. Soy wax experienced an increase in melting and solidification temperatures with a percentage increase, Tm_soywax 9%, and Ts_soywax 13%, respectively, after testing up to 5000 cycles, which represented the application of the PCM for approximately 13 years. Soy wax was synthesized with nanoparticles, such as graphene and MAXene, to increase the effectiveness of soy wax as a TES material by increasing thermal conductivity. 

Experimental Methods

2.1. Sample Preparation

       Soy wax has a melting point of 43.92°C with a latent heat of 117.59 J/g and a solidification point of 38.49 °C with a latent heat of 122.18 J/g (Trisnadewi et al., 2021). This PCM material was synthesized with graphene nanoparticles in the form of a black powder purchased from XFNANO-China type XFQ021. It had an electrical conductivity of 800–1100 S/cm, an apparent density of 0.09–0.13 g/cm3, and a tap density of 0.13–0.16 g/cm3. Another nanoparticle sample, MAXene Ti3AlC2, was purchased from 2D Semiconductors (USA). In general, a MAX phase is initially formed by the formula Mn+1AXn, where n = 1, 2, or 3. M is an early transition metal, A is a group of 13 or 14 elements, and X is either carbon or nitrogen (Barsoum, 2000).

       The mixing and ultra-sonification were used to synthesize soy wax with nanoparticles. The synthesis processes of soy wax+graphene and soy wax+MAXene are shown in Figure 1 (a), and the synthesis result is shown in Figure 1 (b). The first step involved weighing the mass of nanoparticles using Fujitsu FSR-A320 and soy wax with three percentage variations, 0.1, 0.5, and 1 wt.%, referring to Equation (1). Then, soy wax was melted until it was in liquid form using Stuart CB162. In the third step, the weighed nanoparticles were placed in a beaker, and the soy wax liquid was poured. The fourth step involved mixing and the synthesis was carried out using a magnetic stirrer for 1 h with stable heating during a stirring speed of 100 rpm, followed by ultra-sonification for 2 h using a 20 kHz 950 W ultrasonic processor.


Figure 1 Nano-PCM synthesis process (a), Synthesis of soy wax+graphene & soy wax+Ti3AlC2 (b)

2.2. Characterization and property testing method
        The characterization of composite nano-PCMs is important for understanding the impact of nanoparticles. The nature of the functional groups, their interactions with the molecular architecture of the support matrix in the composite, and other chemical properties of the nano-PCM were confirmed using an FT-IR Nicolet™ iS50. The material's physical properties were characterized using SEM-EDS to determine the mixed specimens' topography, morphology, composition, crystallography, and elemental composition. In this test, SEM-EDS was used with a voltage of 20 kV and a resolution of 512 × 384 pixels. The instrument used to measure the thermal conductivity of the nano-PCM was a C-Therm TCI thermal conductivity analyzer with a testing range of 0–100 W/mK. The modified transient plane source (MTPS)-ASTM D7984 measurement method was used with a test temperature range of -50–200oC, time testing range 0.8–3 s, precision better than 1%, and accuracy better than 5%. The DSC method was used to measure the thermal energy storage behavior of the PCM and composites, including the melting temperature (Tm), solidification temperature (Tf), latent heat of melting (Hm), and latent heat of solidification (Hf). The DSC (ASTM F 2625-10) measurements were conducted at 5 °C/min heating and cooling rates and in the temperature ranges of 10–120°C and 120–10°C and were held for 5 min at 120°C in air.

Results and Discussion

    The chemical structure of PCM composites was analyzed by FTIR spectroscopy. Figure 2 shows the peaks for pure soy wax (a), soy wax adding graphene (b), and Ti3AlC2 (c) with various mass percentages. Pure soy wax has an absorption peak of 2848-2955 cm-1 which indicates the presence of strain vibrations (C-H) of alkanes (Trisnadewi et al., 2021). The absorption peak of soy wax is at 2916 cm-1, which indicates the strong strain frequency of the CH3, CH2, and C-H functional groups (Pethurajan et al., 2018). Soy wax has an absorption peak in 1702–1738 cm-1, which indicates the absorption of the strain vibration of the carboxylate group (C=O). After synthesizing the spectra of the PCM samples, soy wax+graphene (Figure 2(b)) and soy wax+ Ti3AlC(Figure 2(c)) show similar peak spectra to those of pure soy wax. The transmittance value decreases with an increase in the weight of the nanoparticles. This decrease indicates a decrease in the percentage of functional groups in soy wax owing to the addition of nanoparticles. This also shows an increase in the presence of nanoparticles in the mixture as the resulting transmittance value decreases. Based on the FTIR results, the addition of graphene and MAXene does not produce any new peaks. These results indicate no chemical interaction between soy wax and graphene or MAXene after the synthesis process.


Figure 2 FTIR spectra of pure soy wax (a), soy wax + graphene (b), soy wax + Ti3AlC2 (c)

       The morphology of the nano-PCM mixture was analyzed using SEM-EDS. Figure 3 (a) shows the SEM images of the mixture of soy wax and graphene nanoparticles at a magnification of 5 µm. The morphology is multilayer or stack-like. There are lumps, the texture is not very rough, and the corners of the graphene sheet are not very sharp. Figure 4 (a) shows the results of the SEM test of the mixture of soy wax and Ti3AlC at a magnification of 5 µm. When compared with graphene, Ti3AlC has a wider and more structured sheet. The texture shown in the Ti3AlC SEM results is almost the same as that of graphene, i.e. sheets with angles that are not too sharp. The difference is that the particle size of graphene is smaller than that of Ti3AlC. Thus, when viewed from the perspective of particle size, it can be observed that the thermal conductivity of the mixture of soy wax and graphene is greater. The multi-layered morphology of graphene and MAXene allows more nanoparticles to be adsorbed onto the surface of soy wax. When more nanoparticles are adsorbed, the stability of the soy-wax material is greater.

       Figures 3 (b) and 4 (b) show the results of the EDS mapping test, which aimed to determine the elements that constituted the mixture. Both EDS mapping results show that these two mixtures have very high C (carbon) content. In addition to similarities in element C, these two materials contain O. The EDS results of these two samples follow the results of the FTIR test, which shows the presence of hydrocarbon bonds. The difference between these two samples is the Al content of Ti3AlC. Figure 4 (b) shows aluminum scattered along the carbon sheet. The presence of carbon and aluminum in PCM soy wax can increase the thermal conductivity of the material, increasing the ability of PCM soy wax to conduct heat. Based on the EDS test, the carbon value of MAXene can approach the carbon content in graphene, namely 82.2 wt.% in Ti3AlC and 84.49 wt.% in graphene. These results indicate that MAXene Ti3AlC is feasible and has excellent potential for use as a supporting material with characteristics like those of graphene.


Figure 3 (a). Morphology of a mixture of soy wax and graphene nanoparticles; (b) mapping distribution elements of graphene


Figure 4 (a). Morphology of a mixture of soy wax and Ti3AlC2 nanoparticles; (b) mapping distribution elements of Ti3AlC2

       Thermal conductivity testing was carried out at a temperature of approximately 20oC, and data collection was repeated 10 times to obtain accurate results. The average thermal conductivity test results are shown in Table 1. Figure 5 (a) shows the ratio of the increase in the average thermal conductivity of soy wax after synthesis with graphene and Ti3AlC2. Soy wax+graphene results in an increase of 5% at a mass percentage of 0.5 wt.% with a ratio of 6.01 with pure soy wax. Soy wax+ Ti3AlC2 results in an increase of 4.7% at a mass percentage of 1 wt.% with a ratio of 5.71 with pure soy wax. The results show an increase in thermal conductivity with an increase in the weight of the nanoparticles (Putra et al., 2016). However, a mixture must have an optimal point such that in the event of exceeding the optimum limit, there is no change or deterioration in properties. This condition occurs in the soy wax and graphene mixture, with a decrease of 0.01 W/mK at 1 wt.%.

       The addition of a particular mass fraction of nanoparticles to the PCM results in a decrease in the melting point, solidification point, and latent heat of the PCM (Huang et al., 2017). The graph for the soy wax and graphene mixture shows the same trend for the three mass variations, namely, heat flow degradation and changes in melting point and solidification point, and the same trends are observed for soy wax + Ti3AlC2. Figure 5(b) shows the effect of the nanoparticles on the melting and solidification rates. This demonstrates that the melting temperature of the nano-PCM slowly decreases, but the solidification rate does not change significantly with the addition of nanoparticles. The mixture of soy wax + graphene experiences an increase in melting point concerning that of pure soy wax by 6.4oC and by 5.5oC for the solidification point, with a constant value for each increase in the percentage of graphene. For soy wax + Ti3AlC2, the melting point is increased by 7.4oC, but the solidifying point reduces by 5.3oC from that of pure soy wax. Based on the results of these thermal properties, it is evident that the addition of nanoparticles enhances thermal conductivity but reduces its melting point. The thermal properties and enthalpy of the PCM were investigated using a DSC test. The test results are shown in Figure 6, in which the graphs are generated using dynamic mode (Barreneche et al., 2013). The enthalpy value based on the DSC result is representative of the peak area, but this result shows the data with  unit. Based on these results, the peak melting area of soy wax + graphene decreased while the wt% of nanoparticles increased and was the same as that of soy wax + Ti3AlC2.

       In contrast to the solidification peak area, the soy wax + graphene mixture decreased after the wt% of 0.5 wt% by 560.1 µVs/mg but increased after 1 wt% to 585.9, but in the soy wax + Ti3AlC2 mixture, there was a linear decrease. From the values of thermal conductivity, melting, and solidification temperatures, the melting and solidification peak areas show the same pattern where at 0.5 wt% there is a decrease and a non-linear increase with an increase in the proportion of the amount. Thus, it can be solved that the concentration of 0.5 wt% graphene+soy wax mixture is the maximum/best mixture to increase the thermal properties of soy wax.

Figure 5 (a) The enhancement percentage of thermal conductivity of soy wax + graphene and soy wax + Ti3AlC2, (b) Effect of nanoparticles on melting and solidification temperatures of nano-PCMs