Published at : 25 Nov 2019
Volume : IJtech Vol 10, No 6 (2019)
DOI : https://doi.org/10.14716/ijtech.v10i6.3695
|Eny Kusrini||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Shella Wu||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Bambang Heru Susanto||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Maya Lukita||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Misri Gozan||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Muhammad Dicky hans||Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus UI-Depok, Depok 16424, Indonesia|
|Arif Rahman||Department of Chemistry, Faculty of Mathematics & Natural Sciences, Universitas Negeri Jakarta, Rawamangun 13220, Indonesia|
|Volkan Degirmenci||School of Engineering, The University of Warwick, Coventry CV4 7AL, UK|
|Anwar Usman||Department of Chemistry, Faculty of Science, Universiti Brunei Darussalam, Jalan Tungku Link, Gadong BE1410, Negara Brunei Darussalam|
This study examined the effects of acid/base activation and chitosan coating on clinoptilolite zeolite as an adsorbent for biogas purification from palm oil mill effluent (POME) using simultaneous absorption–adsorption methods. The effects of chitosan concentration in the clinoptilolite zeolite/chitosan (ZAC) composites were studied to determine the best type of adsorbent for purifying biogas to obtain the highest methane (CH4) concentration: the biogas produced from POME via an anaerobic digestion process had a CH4 concentration of 87% and a carbon dioxide (CO2) concentration of 13%. In this study, the Ca(OH)2 solution was used for the absorption process, and the ZAC composite was used as the adsorbent in the adsorption process. To enhance the adsorption efficiency of the adsorbent when purifying biogas, clinoptilolite zeolite (ZA) was activated using strong acid (HCl) and base (NaOH) in various concentrations (ranging from 1–3 M), calcination at 450°C for 2 h, and coating with chitosan concentrations (ranging from 0.25–1 v/v%). The ZA was coated with chitosan to increase its adsorption efficiency, as chitosan contains high levels of amine and hydroxyl groups that interact with CO2 impurities and form carbamic acid, ultimately producing carbamate salt. The composition of biogas before and after treatment was analyzed using gas chromatography. Overall, the final content of the biogas after the purification process with absorption using the Ca(OH)2 solution and adsorption in a fixed-bed column using the ZAC2-0.5 composite was 0.42% CO2 and 99.58% CH4. The purified biogas had a very high methane gas content; thus, this study’s findings suggest that purified biogas can be used as a clean energy source for wider industrial applications.
Biogas purification; Chitosan; Clinoptilolite zeolite; Composite; Methane content; Simultaneous absorption–adsorption
The production and utilization
of biogas for green energy in wider industrial applications and cleaner fuels
has attracted a great deal of attention for many countries. It is necessary to
biogas to enhance its energy content; this is done by removing impurities such
as CO2, H2S, and water vapor. This increases the methane
purity of the biogas, making it possible
to inhibit corrosion when used in pipelines and other instruments such as column
reactor and machine. This also has implications for new green energy, reducing
the economic losses from maintenance and operational costs for this devices and
also pipelines (Bak et al., 2019).
In contrast, enriching biogas has the potential to replace natural gas in future altogether, as biogas can be used in electricity production in co-generation with heat and power (Kadam & Panwar, 2017). The amount of CH4 is increased and concentrated in enriched biogas to achieve a similar composition and the same standards as a natural gas, allowing it to be used as transportation fuel and in pipeline systems for household use. Biogas can also be converted into a liquid form using cryogenic freezing, chilling the gas to -80°C and then further chilling it to -162°C (Kadam & Panwar, 2017). This method makes it more economical to compress and transport the biogas over longer distances for further applications.
Huge increases in the price of fossil fuels since 2008 due to the economic crisis have prompted researchers to study methods of upgrading biogas since 19th century (Osman et al., 2019). Enriching biogas involves removing unwanted gases such as CO2, H2S, and water vapor to increase its calorific value and specific heat and minimize its corrosive nature caused by the acidic gases it contains (Leonzio, 2016; Kusrini et al., 2017). Its high CO2 content results in low calorific value, and further purification of the resultant gas to remove CO2 is required. Some methods for purification include pressure swing adsorption, adsorption, and chemical absorption (Ackley et al., 2003; Alonso-Vicario et al., 2010; Leonzio, 2016). Masyhuri et al. (2013) purified biogas using a Ca(OH)2 solution. Kusrini et al. (2018) captured CO2 using graphite waste composites and ceria. In terms of the adsorptive purification of biogas, researchers have used adsorbents containing physisorption, such as activated carbon and zeolite. Chemisorption efforts have utilized iron oxide and iron oxide hydroxide (Bak et al., 2019). The most-used substances for biogas purification are activated carbon and zeolite (Alonso-Vicario et al., 2010; Peluso et al., 2019).
This study successfully modified clinoptilolite zeolites via acid/base activation, calcination, and coating with chitosan and applied them as an adsorbent to purify biogas from POME using simultaneous absorption and adsorption methods. The modification changed the structure of the clinoptilolite zeolites, making them highly effective as an adsorbent to remove CO2 from biogas. The final content of the biogas after the purification process with absorption with the Ca(CO)2 solution and adsorption in a fixed-bed column using the ZAC2-0.5 composite was the most effective, with a composition of CH4 (99.58%) and CO2 (0.42%). The resultant purified biogas had a very high methane gas content (99.58%) and very low concentration of impurities. This study recommends that biogas produced via purification using a Ca(OH)2 solution and a ZAC-0.5 composite be used as a clean energy source for wider industrial applications.
We thank the Ministry of
Agriculture, Republic of Indonesia through Grant of Kerjasama Kemitraan
Penelitian dan Pengembangan Pertanian Nasional (KKP3N) No.
Ackley, M.W., Rege, S.U., Himanshu, S., 2003. Application of Natural Zeolites in the Purification and Separation of Gases. Microporous and Mesoporous Materials, Volume 61(1–3), pp. 25–42
Alonso-Vicario, A., Ochoa-Gómez, J.R., Gil-Río, S., Gómez-Jiménez-Aberasturi, O., Ramírez-López, C.A., Torrecilla-Soria, J., Domínguez, A., 2010. Purification and Upgrading of Biogas by Pressure Swing Adsorption on Synthetic and Natural Zeolites. Microporous and Mesoporous Materials, Volume 134(1–3), pp. 100–107
Bak, C.-u, Lim, C.-J., Kim, Y.-D., Kim, W.-S., 2019. Multi-stage Adsorptive Purification Process for Improving Desulfurization Performance of Biogas. Separation and Purification Technology, Volume 227, pp. 1–9
Harsono, S.S., Grundmann, P., Soebronto, S., 2014. Anaerobic Treatment of Palm Oil Mill Effluents: Potential Contribution to Net Energy Yield and Reduction of Greenhouse Gas Emissions from Biodiesel Production. Journal of Cleaner Production, Volume 64, pp. 619–627
Kadam, R., Panwar, N.L., 2017. Recent Advancement in Biogas Enrichment and its Applications. Renewable and Sustainable Energy Reviews, Volume 73, pp. 892–903
Kowalczyk, P., Sprynskyy, M., Terzyk, A.P., Lebedynets, M., Namiesnik, J., Buszewski, B., 2006. Porous Structure of Natural and Modified Clinoptilolites. Journal of Colloid and Interface Science, Volume 297(1), pp. 77–85
Kusrini, E., Lukita, M., Gozan, M., Susanto, B.H., Widodo, T.W., Nasution, D.A., Wu, S., Rahman, A., Siregar, Y.D.I., 2016. Biogas from Palm Oil Mill Effluent: Characterization and Removal of CO2 Using Modified Clinoptilolite Zeolites in a Fixed-bed Column. International Journal of Technology, Volume 7(4), pp. 625–634
Kusrini, E., Lukita, M., Gozan, M., Susanto, B.H., Nasutio, D.A., Rahman, A., Gunawan, C., 2017. Enrichment Process of Biogas using Simultaneous Absorption–Adsorption Methods. In: AIP Conference Proceedings
Kusrini, E., Utami, C.S., Usman, A., Nasruddin., Tito, K.A., 2018. CO2 Capture using Graphite Waste Composites and Ceria. International Journal of Technology, Volume 9(2), pp. 287–296
Leonzio, G., 2016. Upgrading of Biogas to Bio-methane with Chemical Absorption Process: Simulation and Environmental Impact. Journal of Cleaner Production, Volume 131, pp. 364–375
Masyhuri, A.P., Ahmad, A.M., Djojowasito, G., 2013. Design of Carbon Dioxide (CO2) Absorbent System in Biogas Flow using Ca(OH)2 Solution. Jurnal Keteknikan Pertanian Tropis dan Biosistem, Volume 1, pp. 19–28
Osman, A.I., Abdelkader, A., Farrell, C., Rooney, D., Morgan, K., 2019. Reusing, Recycling and Up-Cycling of Biomass: A Review of Practical and Kinetic Modelling Approaches. Fuel Processing Technology, Volume 192, pp. 179-202
Peluso, A., Gargiulo, N., Aprea, P., Pepe, F., Caputo, D., 2019. Nanoporous Materials as H2S Adsorbents for Biogas Purification: A Review. Separation and Purification Technology, Volume 48, pp. 78–89
Tetteh, E., Amano, K.O.A., Asante-Sackey, D., Armah, E., 2018. Response Surface Optimisation of Biogas Potential in Co-digestion of Miscanthus Fuscus and Cow Dung. International Journal of Technology, Volume 9(5), pp. 944–954