A Study of the Structural and Electrochemical Properties of Li3PO4-MMT-PVDF Composites for Solid Electrolytes

Batteries on the market today still use liquid-type electrolytes, which can result in safety issues caused by electrolyte leakage. Therefore, studies that search for solid-state electrolytes are important for resolving these issues. In this research, a composite of lithium phosphate-montmorillonite-polyvinylidene fluoride (Li₃PO₄-MMT-PVDF) has been characterized with the aim of detecting the electrochemical performance of Li₃PO₄ with the addition of MMT. Li₃PO₄ samples were prepared through a solid-state reaction, which was then mixed with MMT, which had a composition ranging from 5 wt% to 20 wt%, and 1 wt% PVDF as a binder. This characterization was conducted with structural, morphological, and electrochemical aspects. The structural test showed that the X-ray diffraction (XRD) pattern was dominated by Li₃PO₄ peaks and MMT aluminosilicates. The electrochemical characterization indicated that the conductivity value of the composites was greater than that of Li₃PO₄. The highest conductivity was achieved with a 15 wt% MMT addition, with a dielectric-constant value of 74.9 at a frequency of 10 kHz.

Composites; Electrochemical Impedance Spectroscopy; Lithium Phosphate; Montmorillonite; Solid Electrolyte