• International Journal of Technology (IJTech)
  • Vol 6, No 7 (2015)

Synthesis of Aligned Carbon Nanotube (ACNT) through Catalytic Decomposition of Methane by Water-Assisted Chemical Vapor Deposition (WACVD)

Synthesis of Aligned Carbon Nanotube (ACNT) through Catalytic Decomposition of Methane by Water-Assisted Chemical Vapor Deposition (WACVD)

Title: Synthesis of Aligned Carbon Nanotube (ACNT) through Catalytic Decomposition of Methane by Water-Assisted Chemical Vapor Deposition (WACVD)
Praswasti PDK Wulan, Widodo Wahyu Purwanto, Mahmud Sudibandriyo

Corresponding email:


Published at : 30 Dec 2015
Volume : IJtech Vol 6, No 7 (2015)
DOI : https://doi.org/10.14716/ijtech.v6i7.1227

Cite this article as:

Wulan, P.P., Purwanto, W.W., Sudibandriyo, M., 2015.Synthesis of Aligned Carbon Nanotube (ACNT) through Catalytic Decomposition of Methane by Water-Assisted Chemical Vapor Deposition (WACVD). International Journal of Technology. Volume 6(7), pp. 1119-1127



661
Downloads
Praswasti PDK Wulan Sustainable Energy Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus Baru UI Depok, Depok 16424, Indonesia
Widodo Wahyu Purwanto Sustainable Energy Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus Baru UI Depok, Depok 16424, Indonesia
Mahmud Sudibandriyo Sustainable Energy Research Group, Department of Chemical Engineering, Faculty of Engineering, Universitas Indonesia, Kampus Baru UI Depok, Depok 16424, Indonesia
Email to Corresponding Author

Abstract
Synthesis of Aligned Carbon Nanotube (ACNT) through Catalytic Decomposition of Methane by Water-Assisted Chemical Vapor Deposition (WACVD)

The production of Carbon Nanotubes (CNT) has a problem with the limited results of Aligned CNT (ACNT) products, due the fact that an effective and economical method has not yet been discovered. This research used catalytic decomposition of methane with the Water-Assisted Chemical Vapor Deposition (WA-CVD) method by using a bench-scale plate structured catalyst reactor and a fixed bed reactor. The Fe-Ni/Al2O3 Catalyst prepared by sol-gel/dip-coating and Ni-Cu-Al Catalyst prepared by co-precipitation were used to make the CNT. Transmission Electron Microscope (TEM) results show there are various types of nanocarbons produced, such as CNT, bamboo-shaped CNT and also quasi-spherical carbon onion shapes. Based on comparative results without adding the water vapor method, ACNT, which were obtained with WA-CVD, tend to grow vertically, even though they have not yet formed neat and uniform shapes. In addition, an increased number of CNT have high purity results. It shows that the role of water vapor significantly improves the quality of CNT.

Aligned CNT, Catalytic decomposition of methane, Water-Assisted Chemical Vapor Deposition (WA-CVD)

References

Cao, A., Zhang, X., Xu, C., Liang, J., Wu, D., Wei, B., 2001. Aligned Carbon Nanotube Growth Under Oxidative Ambient. Journal of Material Research, Volume 16(11), pp. 3107–3110

Endo, M., Ijima, S., Dresselhaus, M. S., 1996. Carbon Nanotubes. Oxford, UK : Elsevier Science Ltd

Grujicic, M., Cao, G., Gersten, B., 2002. An Atomic-scale Analysis of Catalytically-assisted Chemical Vapor Deposition of Carbon Nanotubes. Materials Science and Engineering, Volume B94, pp. 247–259

Hata, K., Futaba, N.D., Mizuno, K., Namai, T., Yumura, M., Iijima, S., 2004. Water-assisted Highly Efficient Synthesis of Impurity-free Single-walled Carbon Nanotubes. Science, Volume 306, pp. 1362–1364

Ko, C., Lee, C., Ko, F., Chen, H., Chu, T., 2004. Highly Efficient Microwave-assisted Purification of Multi-walled Carbon Nanotubes. Microelectronic Engineering, Volume 73–74 , pp. 570–577

Li, W.Z., Xie, S.S., Qian, L.X., Chang, B.H., Zou, B.S., Zhou, W.Y., Zhao, R.A., Wang, G., 1996. Large-Scale Synthesis of Aligned Carbon Nanotubes. Science, Volume 274(5293), pp. 1701–1703

Patole, S.P., Alegaonkar, P.S., Lee, H., Yoo, J., 2008. Optimization of Water Assisted Chemical Vapor Deposition Parameters for Super Growth of Carbon Nanotubes. Carbon, Volume 46, pp. 1987–1993

Qian, W., Liu, T., Wang, Z., Hao, Y., Li, Z., Wei, F., Luo, G., 2003. Effect of Adding Nickel to Iron-Alumina Catalysts in the Morphology of As-Grown Carbon Nanotubes. Carbon, Volume 41, pp. 2487–2493

Rong, X., 2009. Acetylene-accelerated Alcohol Catalytic Chemical Vapor Deposition Growth of Vertically Aligned Single-walled Carbon Nanotubes. Journal of Physical Chemistry, Volume 113, pp. 7511–7515

Seah, C., Chai, S., Mohamed, A.R., 2011. Synthesis of Aligned Carbon Nanotubes. Carbon, Volume 49, pp. 4613–4635

Tohji, K., Goto, T., Takahashi, H., Shinoda, Y., Shimizu, N., Jeyadevan, B., Matsuoka, I., Saito, Y., Kasuya, A., Ohsuna, T., Hiraga, K., Nishina, Y., 1996. Purifying Single-walled Nanotubes. Nature 10, Volume 383, pp. 679–689 DOI: 10.1038/383679a0

Purwanto, W.W., Wulan, P.P., Paramitha, S.S., 2011. Applications of Ultrasonic and Microwave for Purifying Carbon Nanotubes are Synthesized by Catalytic Decomposition of Methane (in Bahasa). Jurnal Purifikasi, Volume 12(2), pp. 75–82

Wang, H., NG, K.M., Hu, X., Feng, J., 2013. Synthesis of Aligned Carbon Nanotubes on Double-sided Metallic Substrate by Chemical Vapor Deposit in Hongkong. The Journal of Physical Chemistry, Volume 111(34), pp. 12617–12624

Wulan, P.P., Purwanto, W.W., Muharam, Y., Paramitha, S.S., Listiani, E., 2011. The Effect of Reaction Time on the Quality of Hydrogen and Carbon Nanotubes Produced through Catalytic Decomposition of Methane. Journal of Sustainable Energy & Environment Volume 2, pp. 7–10

Yang, L., Lu, T., Xu, H., Zhang, W., Ma, B., 2010. A Study on the Effect Factors of Sol-Gel Synthesis of Yttrium Aluminum Garnet Nanopowders. Journal of Applied Physics, Volume 107, pp. 064903-1–8