• Vol 9, No 5 (2018)
  • Metalurgy and Material Engineering

Nanostructure Properties And Dye-sensitized-solar-cell open-circuit Voltage of A TiO2 Aerogel and Pre-Hydrothermally Treated Xerogels

Bambang Priyono, Akhmad Herman Yuwono, Badrul Munir, Muhammad Hasan Mustofa, Faizah


Cite this article as:
Priyono, B., Yuwono, A.H., Munir, B., Mustofa, M.H., Faizah.,2018. Nanostructure Properties And Dye-sensitized-solar-cell open-circuit Voltage of A TiO2 Aerogel and Pre-Hydrothermally Treated Xerogels . International Journal of Technology. Volume 9(5), pp. 972-982
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Bambang Priyono - Metalurgy and Material Engineering, Universitas Indonesia
- Research Group on Advanced Vehicle FTUI
Akhmad Herman Yuwono Metalurgy and Material Engineering, Universitas Indonesia
Badrul Munir Metalurgy and Material Engineering, Universitas Indonesia
Muhammad Hasan Mustofa Metalurgy and Material Engineering, Universitas Indonesia
Faizah Metalurgy and Material Engineering, Universitas Indonesia
Email to Corresponding Author

Abstract
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Dye-sensitized solar cells (DSSCs) are third-generation photovoltaic devices, which are considered to be a very promising renewable-energy source that offers an alternative to fossil fuels due to their low cost, ease of production, and eco-friendliness. One of the most important components in DSSCs is the TiO2 layer, which serves as an active inorganic semiconductor oxide for photoelectron activity. Herein, TiO2 nanoparticles were synthesized via a sol-gel process using titanium tetra-n-butoxide, ethanol, hydrochloric acid, and deionized water at molar ratios of 0.4:0.83:1:1.39 upon sol preparation, followed by hydrothermal processes at three different temperatures (i.e., 100°C, 120°C, and 150°C); ambient drying; and multi-step calcination. For comparison, TiO2 aerogel nanoparticles were also prepared via supercritical extraction followed by multi-step calcination. The samples were analyzed by X-ray diffraction, Brunauer–Emmett–Teller surface-area measurements, UV–Vis spectroscopy in the diffuse-reflectance-) mode, and scanning electron microscopy. The results showed that the pre-hydrothermally treated samples exhibited band-gap energies of 3.34, 3.29, and 3.32 eV after treatment at 100°C, 120°C, 150°C, respectively, whereas the aerogel sample had a band-gap energy of 3.33 eV. Open-circuit-voltage measurements revealed that the DSSCs fabricated by pre-hydrothermal treatment at 120°C generated a higher voltage (320 mV) than aerogel cells (21 mV).

Aerogel; Multi-step calcination; Open circuit voltage; Pre-hydrothermal treatment; Supercritical extraction

Introduction

The use of renewable energy is a key way to overcome the world’s energy crisis. Dye-sensitized solar cells (DSSCs) are one of the most attractive solar-energy harvesting methods due to their low cost, high photon conversion efficiency, and good stability (O’Regan & Grätzel, 1991). Many efforts have been made to improve the performance of DSSCs (Khan et al., 2017) with an important approach being the optimization of the photoanode. In this case, the performance improvement relates to the base material, which is influenced by the structure of the oxide layer having a high surface area to absorb sensitizing dyes and maximize the performance as required. One of the most commonly used semiconductor layers in DSSCs is TiO2 (Sofyan et al., 2017). TiO2 nanoparticles have gained importance for the fabrication of photoanodes, which comprise a monolayer of highly porous material (Sugathan et al., 2015).  The photoelectrode in a DSSC is sometimes also referred to as the working electrode, and under commercial development, it generally includes titania nanoparticles. The crystal phase of the TiO2 particles used in DSSCs is generally the anatase phase because of its high dye-absorbance properties (Nursama & Muliani, 2012).

In addition, the use of TiO2 is excellent from the viewpoint of its optical properties because it has a band-gap energy of ~3.2 eV with a wavelength of <380 nm (Langlet et al., 2002). Furthermore, the cystallinity and high-surface-area properties of the TiO2 anatase nanostructure are preferred due to the high photoactivity of the material. Many studies are focusing on the methods to prepare TiO2 to meet the required properties for photoanodes, e.g., by solid-state, sol-gel routes with various thermal treatments. The sol-gel method is one of the most useful techniques for synthesizing nanoparticles with high purity of precursor to obtain a high surface area, large pore volume, and uniform pore-size distribution.

A hydrothermal treatment was applied here to prepare TiO2 anatase [instead of the supercritical extraction (SCE) method] because it offers several advantages, including high purities, a good distribution of the material, and increased photoactivity and crystallite size (Dai et al., 2010). Earlier studies on hydrothermal synthesis have shown good results for titanium-tetra-isopropoxide, which exhibited an open circuit voltage of 69.33 mV and a crystallite size of 12.46 nm (Yuwono et al., 2010). In contrast, the SCE technique involves CO2 as the extraction solvent, which has the potential to augment the surface area of the nanoparticles but may also lead to a low degree of crystallinity. Thus, to overcome the crystallinity issue, both of them must be calcinated at various temperatures and different conditions. A modification of the simple nanostructure-synthesis process used in this study to obtain TiO2 is the bottom-up method (sol-gel), as described above, which includes supercritical and hydrothermal treatments followed by gradual calcination. Synthesizing nanoparticles using the sol-gel method can improve the properties of TiO2 structures regarding the degree of crystallinity, surface area, and photoactivity. Therefore, this study aims at designing a better preparation technique for optimum results, perform both treatments to improve the crystallite structure, and reduce the size of the band-gap-energy (Kim et al., 2007), coupled with a gradual calcination in some condition.

In our previous study, TiO2 nanoparticles were successfully synthesized from titanium tetra-n-butoxide using the sol-gel method, followed by supercritical extraction and multi-step calcination, to obtain a highly crystalline aerogel with a vast surface area and increased photoelectrochemical sensitivity (Priyono et al., 2013). In the present study, the preparation technique has been modified to improve the nanostructure properties for use in DSSC devices. The method uses a xerogel combined with a hydrothermal process and followed by multi-step calcination to improve the crystallinity of all the samples while maintaining a minimum loss in surface area due to crystal growth. The results were then compared to those obtained for a TiO2 aerogel prepared by the SCE method with the same multi-step calcination process as that demonstrated by (Brodsky & Ko, 1994).

The correlation between TiO2 nanostructure properties such as crystallite size, surface area, and band-gap energy and the performance of the material as a semiconductor for better and more efficient DSSCs was investigated.

Conclusion

All the samples resulting from this research had a nanocrystalline structure and were successfully assembled into DSSCs to study their ability to convert light into electrical energy, as shown by their Voc values.

The properties of the TiO2 aerogel reported herein exceeded those of materials presented in previous research, exhibiting a larger surface area and achieving a high enough crystallinity. Furthermore, compared to samples submitted to pre-hydrothermal treatment, the aerogel had the highest surface area (110.31 m2/g) and a crystallite size of 8.07 nm.

Regarding the crystallite size, the largest structures were obtained by pre-hydrothermal treatment at 150°C (9.73 nm), with a surface area of 82.17 m2/g. The size of the samples treated at 120°C was 7.79 nm (surface area: 85.43 m2/g) and that of the materials treated at 100°C was 7.45 nm (in this case the surface area was only 71.31 m2/g). Pre-hydrothermal treatment was performed to suppress the fast development of stiff Ti–OH structures, which lead to largely amorphous particles. This treatment transforms the Ti–OH network into a flexible Ti–O–Ti arrangement. Subsequent multi-step calcination enhances the crystallinity of the resulting TiO2 particles further, thus confirming the findings of previous researchers.

Voc measurements revealed that DSSCs fabricated using the aerogel provided 21 mV. The best results were obtained for the pre-hydrothermally treated sample prepared at 120°C (320 mV), followed by the samples treated at 150° and 100°C, respectively.

Acknowledgement

The authors would like to acknowledge financial support from the Directorate of Research and Community Services - Universitas Indonesia (DRPM-UI) through Hibah Riset Madya Universitas Indonesia under contract no. DRPM/RII/175/RM-UI/2013.

 

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